Palladium-catalyzed chemoselective anaerobic oxidation of N-heterocycle-containing alcohols

• Kuriyama, Masami

• Nakashima, Sho

• Miyagi, Tsubasa

• Sato, Kanako

• Yamamoto, Kosuke

• Onomura, Osamu

抄録

The palladium-catalyzed anaerobic oxidation for N-heterocycle-containing alcohols has been developed with chloroarenes as oxidants. In this process, primary and secondary alcohols were selectively oxidized even in the presence of cyclic amines as well as heteroarenes, and primary, secondary, and tertiary amino groups were found to be well tolerated. Moreover, a gram-scale chemoselective oxidation was achieved in addition to a double oxidation of a diamino diol.

Organic Chemistry Frontiers, 5(15), pp.2364-2369; 2018

収録刊行物

• Organic Chemistry Frontiers

  Organic Chemistry Frontiers 5 (15), 2364-2369, 2018-08-07

  Royal Society of Chemistry

詳細情報

• CRID: 1050287297263952000
• NII論文ID: 120006987984
• ISSN: 20524110
• ISSN: 20524129
• HANDLE: 10069/38545
• Web Site: https://nagasaki-u.repo.nii.ac.jp/records/1286
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles