Probing dynamics of carbon dioxide in a metal-organic framework under high pressure by high-resolution solid-state NMR

• Inukai, Munehiro

• Kurihara, Takuya

• Noda, Yasuto

• Jiang, Weiming

• Takegoshi, Kiyonori

• Ogiwara, Naoki

• Kitagawa, Hiroshi

• Nakamura, Koichi

抄録

The application of high-resolution NMR analysis for CO2 adsorbed in an MOF under high pressure is reported for the first time. The results showed that CO2 adsorbed in MOF-74 had a unusual slow mobility (τ ~ 10-8 s). CO2–CO2 interactions suppressed the mobility of CO2 under high pressure, which, in turn, would have contributed to the stability of CO2 at adsorption sites.

収録刊行物

• Physical Chemistry Chemical Physics

  Physical Chemistry Chemical Physics 22 (26), 14465-14470, 2020-04-21

  The Royal Society of Chemistry

キーワード

• Physical and Theoretical Chemistry
• General Physics and Astronomy

詳細情報

• CRID: 1050287827473240192
• NII論文ID: 120007027673
• NII書誌ID: AA11301773
• ISSN: 14639076
• ISSN: 14639084
• DOI: 10.1039/d0cp01216e
• Web Site: http://repo.lib.tokushima-u.ac.jp/114711
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP01216E
• 本文言語コード: en
• 資料種別: journal article
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