Synthesis of pyrrole-based poly(arylenevinylene)s via Rh-catalyzed dehydrogenative direct alkenylation

• 桑原, 純平

• 神原, 貴樹

• Saito, Hitoshi

• Kuwabara, Junpei

• Yasuda, Takeshi

抄録

Polycondensation via Rh-catalyzed dehydrogenative direct alkenylation was conducted. The introduction of a directing group, such as a 2-pyrimidinyl substituent, to the pyrrole monomer promoted a polycondensation reaction, giving rise to corresponding poly(arylenevinylene)s with a trans-configuration in good yields. The absorption and electronic properties of the polymers were examined.

収録刊行物

• Polymer Chemistry

  Polymer Chemistry 7 (16), 2775-2779, 2016-04

  The Royal Society of Chemistry

詳細情報

• CRID: 1050282677519311232
• NII論文ID: 120007135414
• ISSN: 17599954
• HANDLE: 2241/00143153
• Web Site: https://tsukuba.repo.nii.ac.jp/records/38484
• 本文言語コード: en
• 資料種別: journal article
• データソース種別:
  • IRDB
  • CiNii Articles