Synthesis of pyrrole-based poly(arylenevinylene)s via Rh-catalyzed dehydrogenative direct alkenylation

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Abstract

Polycondensation via Rh-catalyzed dehydrogenative direct alkenylation was conducted. The introduction of a directing group, such as a 2-pyrimidinyl substituent, to the pyrrole monomer promoted a polycondensation reaction, giving rise to corresponding poly(arylenevinylene)s with a trans-configuration in good yields. The absorption and electronic properties of the polymers were examined.

Journal

  • Polymer Chemistry

    Polymer Chemistry 7 (16), 2775-2779, 2016-04

    The Royal Society of Chemistry

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