Liquid–liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(<scp>ii</scp>) complex

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  • Liquid-liquid interface-promoted formation of a porous molecular crystal based on a luminescent platinum(ii) complex

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Porous molecular crystals (PMCs) should function as new-generation functional porous materials, but the selective crystallisation of PMCs is still difficult. Herein we demonstrate that the liquid-liquid interface between the MeOH/H2O mixture and alkanes promotes the crystallisation of a Pt(ii)-based PMC, rather than the nonporous form. This new crystallisation method allows control of not only the porosity but also the luminescence of the Pt(ii) complex crystal.

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