Transition-metal-free Nucleophilic 211At-astatination of Spirocyclic Aryliodonium Ylides

• Matsuoka, Keitaro

• Obata, Honoka

• Nagatsu, Kotaro

• Kojima, Masahiro

• Yoshino, Tatsuhiko

• Ogawa, Mikako

• Matsunaga, Shigeki

Bibliographic Information

Other Title

• Transition-metal-free nucleophilic ²¹¹At-astatination of spirocyclic aryliodonium ylides

Abstract

The transition-metal-free At-211-astatination of spirocyclic aryliodonium ylides via a nucleophilic aromatic substitution reaction is described. This method enables the preparation of At-211-radiolabeled compounds derived from multi-functionalized molecules and heteroarenes in good to excellent radiochemical yields.

Journal

• Organic & biomolecular chemistry

  Organic & biomolecular chemistry 19 5525-5528, 2021-01-04

  Royal Society of Chemistry

Details

• CRID: 1050009295028881024
• NII Article ID: 120007181801
• DOI: 10.1039/d1ob00789k
• ISSN: 14770539
• ISSN: 14770520
• HANDLE: 2115/83759
• Web Site: http://pubs.rsc.org/en/content/articlepdf/2021/OB/D1OB00789K
• Text Lang: en
• Article Type: journal article
• Data Source:
  • IRDB
  • Crossref
  • CiNii Articles
  • KAKEN