Complete Oxidation of Ethylene by Co-Modified Mordenites under Microwave Irradiation

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Addition of cobalt oxide (Co<SUB>3</SUB>O<SUB>4</SUB>) as a heating promoter, absorbing microwave energy with high efficiency, was suggested in order to accelerate microwave heating of zeolite adsorbent or catalyst. The effect of the addition of Co<SUB>3</SUB>O<SUB>4</SUB> on the microwave heating of Co-modified mordenites prepared by the impregnation method and physical mixing was investigated. Catalytic oxidation of ethylene on Co-modified mordenites was also examined under microwave irradiation. Co<SUB>3</SUB>O<SUB>4</SUB> promoted microwave heating of the mordenite bed when Co<SUB>3</SUB>O<SUB>4</SUB> and mordenite were mixed physically. The physical mixture with Co<SUB>3</SUB>O<SUB>4</SUB> of 50 wt% was heated up to 518 K by microwave irradiation. The desorption peak of water for pellet type Co-modified mordenite was very sharp in microwave heating after pre-adsorption of water vapor and most of adsorbed water desorbed in the initial stage of the microwave heating. The sharp desorption peak of water indicates that the pelletized sample was heated to higher temperatures than powder one. In the case of the pelletized Co-modified mordenite with Co<SUB>3</SUB>O<SUB>4</SUB> of 75 wt%, adsorbed water on mordenite was almost desorbed during microwave irradiation. Co<SUB>3</SUB>O<SUB>4</SUB> had both functions of the heating promoter and catalyst, and ethylene was removed with high conversion (93%) when the pelletized mixture of Co<SUB>3</SUB>O<SUB>4</SUB> (75 wt%) and mordenite was irradiated by microwave under steady feed of ethylene, water vapor, and oxygen.

収録刊行物

  • JOURNAL OF CHEMICAL ENGINEERING OF JAPAN

    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 38(10), 828-834, 2005

    公益社団法人 化学工学会

各種コード

  • NII論文ID(NAID)
    130000019442
  • NII書誌ID(NCID)
    AA00709658
  • 本文言語コード
    ENG
  • 資料種別
    特集
  • ISSN
    0021-9592
  • NDL 記事登録ID
    7491473
  • NDL 雑誌分類
    ZP1(科学技術--化学・化学工業)
  • NDL 請求記号
    Z53-R395
  • データ提供元
    NDL  J-STAGE 
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