Preparation and Characteristics of Arginine Oleate Liquid Crystal Holding a Large Amount of Water
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- KANEKO Teruhisa
- R/D Control Department, SHU UEMURA INC.
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- YAMAOKA Yurie
- R/D Control Department, SHU UEMURA INC.
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- KAISE Chihiro
- R/D Control Department, SHU UEMURA INC.
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- ORITA Masanori
- Institute of Colloid and Interfacial Science, Tokyo University of Science
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- SAKAI Hideki
- Faculty of Science and Technology, Tokyo University of Science Institute of Colloid and Interfacial Science, Tokyo University of Science
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- ABE Masahiko
- Faculty of Science and Technology, Tokyo University of Science Institute of Colloid and Interfacial Science, Tokyo University of Science
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Solution properties of arginine oleate (ArgOA) were investigated by means of small angle X-ray scattering device, tensiometer, transmittance measuring device, transmission electron microscope, NMR, etc. Whereas arginine stearate which is different in hydrophobic moiety or sodium oleate which is different in counterion from ArgOA formed lamellar liquid crystals in a limited region, ArgOA formed over a wide ranges of temperature and concentration. The surface tension versus concentration curve of ArgOA had two bending points (C1 and C2). When the state of its aqueous solution was observed, transmittance of the aqueous solution decreased in the concentration range of C1 and more and, in the region until C2 where the concentration further increased, particles of several tens nm and several hundreds nm were observed. At concentrations above C2, the viscosity of the aqueous solution began to increase due to the formation of bigger molecular aggregates. The formation of micelles, vesicle-like highly associated aggregates, and lamellar liquid crystals with large amount of water were observed as a result of an increase in concentration of ArgOA.<br>
収録刊行物
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- Journal of Oleo Science
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Journal of Oleo Science 54 (6), 325-333, 2005
公益社団法人 日本油化学会
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詳細情報 詳細情報について
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- CRID
- 1390001204091605376
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- NII論文ID
- 130000055634
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- NII書誌ID
- AA11503337
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- ISSN
- 13473352
- 13458957
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- NDL書誌ID
- 7311604
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
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