Infrared External Reflection Spectra of Mixed Monolayers of Sodium Dodecyl Sulfate and Myristic Acid at an Air/Water Interface.

  • KAWAI Takeshi
    Department of Industrial Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo
  • KAWAGUCHI Fumie
    Department of Industrial Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo
  • KAMIO Hiroaki
    Department of Industrial Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo
  • KON-NO Kijiro
    Department of Industrial Chemistry, Institute of Colloid and Interface Science, Science University of Tokyo

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  • 空気/水界面上におけるドデシル硫酸ナトリウムとミリスチン酸混合単分子膜の赤外外部反射スペクトル(原標題は英語)

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Abstract

The title spectra were measured at various concentrations of SDS. IER spectra demonstrated that conformational order of alkyl chains of SDS and MA and surface composition at the air/water interface was clarified. Conformational order was found to improve on increasing SDS concentration up to [SDS]=3 mM. MA showed essentially no change. The ratio of MA to SDS composition at the interface is exceeded that in bulk solution and decreased at greater SDS.

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