Development of Solid Catalysts Based on Phthalocyanines Generating Singlet Oxygen

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Other Title
  • 一重項酸素を生成するフタロシアニン―固体触媒の開発
  • イチジュウコウ サンソ オ セイセイ スル フタロシアニン コタイ ショクバイ ノ カイハツ

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Abstract

   The pp interaction between phthalocyanines (Pcs) in the solid state induces useful conductivity that is applicable to photoconductors, but it also has disadvantages in terms of reducing the monomeric photochemical properties, i.e., the sharp Q absorption band, intense fluorescence, and ability of singlet oxygen (1Dg) generation. Here, I describe recent methods for preparing silica gel-supported Pcs having both monomeric photochemical properties and high ability of singlet oxygen generation. In particular, magnetic silica gel-supported Pcs can act as the singlet oxygen generator, which can be collected by using magnets.

Journal

  • SEISAN KENKYU

    SEISAN KENKYU 61 (2), 83-86, 2009

    Institute of Industrial Science The University of Tokyo

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