ハイドロタルサイトの合成とその陰イオン交換特性

• 村山 憲弘

  関西大学工学部化学工学科

• 山本 秀樹

  関西大学工学部化学工学科

• 芝田 隼次

  関西大学工学部化学工学科

書誌事項

タイトル別名

• Synthesis of Hydrotalcite and its Anion Exchange Properties
• ハイドロタルサイト ノ ゴウセイ ト ソノ インイオン コウカン トクセイ

抄録

As one of effective usages of the wastes in an aluminum regeneration process, the syntheses of hydrotalcite (HT), which is a functional inorganic material having layered structure of complex hydroxide, were carried out by using aluminum dross and MgCl₂ waste solution as raw materials. Various physical properties such as crystal structure, surface texture and anion exchange properties were measured for the obtained products. The removal of chromic acid ion was investigated with various products.<br>CO₃^2- type HT can be obtained from the aluminum dross and MgCl₂ waste solution by a co-precipitation method. A slight amount of Ca, Na, Si, Fe etc. remains in the product as impurity components. The anion exchange order of HT is as follows; CO₃^2- > SO₄^2- > F^- > Cl^- > NO₃^- ≥ I^-. It is possible to remove chromic acid ion from an aqueous solution with various products by an anion exchange reaction. The Mg/Al complex oxide, which is obtained by calcination of the CO₃^2- type HT at 773 K, is superior to the original HT for the removal of chromic acid ion.

収録刊行物

• 環境資源工学

  環境資源工学 51 (2), 92-98, 2004

  一般社団法人 環境資源工学会

キーワード

• Nature and Landscape Conservation
• Pollution
• Soil Science
• Environmental Chemistry

詳細情報

• CRID: 1390282680184817792
• NII論文ID: 130000103640
• NII書誌ID: AA11907992
• DOI: 10.4144/rpsj.51.92
• ISSN: 13499262
• ISSN: 13486012
• ISSN: http://id.crossref.org/issn/13486012
• HANDLE: 10112/5520
• NDL書誌ID: 6980462
• Web Site: https://kansai-u.repo.nii.ac.jp/records/11313
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I6980462
• 本文言語コード: ja
• データソース種別:
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  • IRDB
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  • KAKEN
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