Kinetics of stripping of N-8-quinolyl-p-dodecylbenzenesulfonamide-copper chelate complex with hydrochloric acid.
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- YOSHIZUKA KAZUHARU
- Department of Organic Synthesis, Kyushu University
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- KONDO KAZUO
- Department of Organic Synthesis, Kyushu University
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- NAKASHIO FUMIYUKI
- Department of Organic Synthesis, Kyushu University
抄録
A kinetic study concerning the stripping of copper chelate complex in toluene with hydrochloric acid was carried out at 303 K, using a stirred transfer cell and pure copper complex prepared from copper and synthesized N-8-quinolyl-p-dodecylbenzenesulfonamide.<br> It was found that the mechanism of copper stripping could not be explained as simply a reverse process of the copper extraction by this extractant from acetate buffer media, due to the reaction between the extractant and hydrochloric acid and the low solubility of the ion pair complex formed by this reaction. Moreover, it was confirmed that the stripping rate was determined by the first step of the interfacial reaction between the copper complex and the acid, and by mass transfer of the copper complex.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 18 (4), 342-348, 1985
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679541396480
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- NII論文ID
- 130000788905
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- COI
- 1:CAS:528:DyaL28Xnt1amtQ%3D%3D
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- ISSN
- 18811299
- 00219592
- http://id.crossref.org/issn/00219592
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可