二塩化1, 3-ビス [2- (アシルアミノ) エチルジメチルアンモニオ] -2-ヒドロキシプロパンの合成と界面活性

• 金 泰成

  大阪大学大学院工学研究科分子化学専攻

• 辰巳 泰我

  大阪大学大学院工学研究科分子化学専攻

• 木田 敏之

  大阪大学大学院工学研究科分子化学専攻

• 中辻 洋司

  大阪大学大学院工学研究科分子化学専攻

• 池田 功

  大阪大学大学院工学研究科分子化学専攻

書誌事項

タイトル別名

• Synthesis and Surface-Active Properties of 1, 3-Bis- [2- (acylamino) ethyldimethylammonio] -2-hydroxypropane Dichloride

抄録

Novel bis [quaternary amidoammonium] salts were easily prepared by reactions of 2- (acylamino) ethyldimethylamine with epichlorohydrin and should prove chemically hydrolyzable due to amido groups in the lipophilic chains. Surface-active properties were determined and compared with those of 2- (acylamino) ethyltrimethylammonium chloride, and mono- and bis [quaternary alkylammonium] salts. Bis [quaternary amidoammonium] salts each possessing 10 to 14 carbon atoms in the acyl chain showed good water solubility. Cmc of 1, 3-bis [2- (dodecanoylamino) ethyldimethylammonio] -2-hydroxy-propane dichloride was smaller by about one order of magnitude than that of 2- (dodecanoylamino) ethyltrimethylammonium chloride with the same acyl chain length, and smaller by about two orders than that of conventional dodecyltrimethylammonium chloride. The bis [quaternary amidoammonium] salts showed lower surface tension at cmc (γ_cmc) than other mono- and bis [quaternary alkylammonium] salts. Foaming ability and foam stability of bis [quaternary amidoammonium] salts having dodecanoyl or tetradecanoyl group in the lipophilic chain were quite high.

収録刊行物

• 日本油化学会誌

  日本油化学会誌 46 (7), 747-753,821, 1997

  公益社団法人 日本油化学会

キーワード

• amido group
• bis [quaternary ammonium] salts
• hydrolysis
• surface-active properties

詳細情報

• CRID: 1390001204093441152
• NII論文ID: 130001015738
• DOI: 10.5650/jos1996.46.747
• ISSN: 18841996
• ISSN: 13418327
• Web Site: https://www.jstage.jst.go.jp/article/jos1996/46/7/46_7_747/_pdf
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可