Titanium(Ⅳ) Chloride-Mediated Ring Cleavage and Michael Addition of 3,3-Dialkylcyclobutanones and 3-〔(Trimethylsilyl)methyl〕-cyclobutanones

• Okuno Ryosuke

  School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University

• Matsuo Jun-ichi

  School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University

• Ishibashi Hiroyuki

  School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University

書誌事項

タイトル別名

• Titanium(IV) Chloride-Mediated Ring Cleavage and Michael Addition of 3,3-Dialkylcyclobutanones and 3-[(Trimethylsilyl)methyl]-cyclobutanones

抄録

β′-Chloro and β′,γ′-unsaturated trichlorotitanium enolates, which were formed in situ by titanium(IV) chloride-mediated ring cleavage of 3,3-dialkylcyclobutanones and 3-[(trimethylsilyl)methyl]cyclobutanones, reacted with enones to give Michael adducts with keeping a labile β′-chloro or β′,γ′-unsaturated group.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 60 (6), 793-797, 2012

  公益社団法人 日本薬学会

キーワード

• cyclobutanone
• Michael addition
• enone
• ring cleavage

詳細情報

• CRID: 1390001204178168064
• NII論文ID: 130001852483
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.60.793
• COI: 1:STN:280:DC%2BC38jgvFaqsQ%3D%3D
• ISSN: 13475223
• ISSN: 00092363
• HANDLE: 2297/31981
• NDL書誌ID: 023666031
• PubMed: 22689434
• Web Site: https://kanazawa-u.repo.nii.ac.jp/records/15050
• Web Site: http://id.ndl.go.jp/bib/023666031
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I023666031
• Web Site: https://www.jstage.jst.go.jp/article/cpb/60/6/60_c12-00175/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • IRDB
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可