Chloropentakis(trichlorostannato)ruthenate(II)

• Hisateru Okuno

  Department of Chemistry, College of Science, Rikkyo (St. Paul’s) University

• Tatsujiro Ishimori

  Department of Chemistry, College of Science, Rikkyo (St. Paul’s) University

• Kunihiko Mizumachi

  Department of Chemistry, College of Science, Rikkyo (St. Paul’s) University

• Haruhiko Ihochi

  Department of Chemistry, College of Science, Rikkyo (St. Paul’s) University

抄録

The cesium and triethylammonium salts of chloropentakis(trichlorostannato)ruthenate(II), Cs4[RuCl(SnCl3)5]·CsCl and (Et3NH)4[RuCl(SnCl3)5], were prepared. Their IR absorption bands near 210 cm−1are thought to be due to the Ru–Sn stretching vibration. The electronic spectra of dilute hydrochloric acid solutions of the complex salts were the same as the spectrum of a single crystal of the cesium salt. This suggests the presence of the complex ion, [RuCl(SnCl3)5]4−, in acid solutions. A hydrolysis product of the complex ion contained ruthenium, tin and chlorine in the atom ratio of 1 : 5 : [α(<1)], and the cesium salt was yielded from a dilute hydrochloric acid solution of the hydrolysis product. The observations show the presence of the Ru–Sn bonds in the complex ion.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 44 (2), 415-417, 1971-02-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219099507328
• NII論文ID: 130001976443
• DOI: 10.1246/bcsj.44.415
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/44/2/415/55954169/bcsj.44.415.pdf
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