Synthesis of Layered Polysilicic Acid–Acrylamide Intercalation Compounds and Polymerization in the Interlayer Spaces

• Tsuneo Yanagisawa

  Department of Applied Chemistry, Waseda University

• Chika Yokoyama

  Department of Applied Chemistry, Waseda University

• Kazuyuki Kuroda

  Department of Applied Chemistry, Waseda University

• Chuzo Kato

  Department of Applied Chemistry, Waseda University

抄録

Layered polysilicic acid–acrylamide intercalation compounds were synthesized by the reaction of H-magadiite (H2Si14O29·xH2O) and H-kenyaite (H2Si20O41·xH2O) with acrylamide saturated aqueous solutions. The formation of the intercalation compounds were ascertained by X-ray powder diffraction, IR, 13C-CP MAS NMR, DTA, and chemical analysis. However, when H-magadiite was used, a part of the intercalated acrylamide molecules was oligomerized during the intercalation. A heat treatment of the layered polysilicic acid–acrylamide intercalation compounds led to a polymerization of the acrylamide in the interlayer spaces.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 63 (1), 47-50, 1990-01-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644033591040
• NII論文ID: 130001980189
• DOI: 10.1246/bcsj.63.47
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/63/1/47/56215004/bcsj.63.47.pdf
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