A New Synthetic Route to Aliphatic and Alicyclic Nitriles via Homolytic Desulfurization of α-(Dithiocarbamoylthio) Nitriles

• Yanagawa Makoto

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Moriya Osamu

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Watanabe Yoshihiko

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Ueno Yoshio

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

• Endo Takeshi

  Research Laboratory of Resources Utilization, Tokyo Institute of Technology

書誌事項

タイトル別名

• A new synthetic route to aliphatic and alicyclic nitriles via homolytic desulfurization of .ALPHA.-(dithiocarbamoylthio) nitriles.

抄録

Chloroacetonitrile was transformed into aliphatic and alicyclic nitriles through (dimethyldithiocarbamoylthio)acetonitrile. The key steps in the synthetic route consisted of mono- and dialkylation via sulfur-stabilized carbanion and homolytic desulfurization using tributyltin hydride.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 61 (6), 2203-2204, 1988

  公益社団法人 日本化学会

キーワード

• General Chemistry

詳細情報

• CRID: 1390001204128437760
• NII論文ID: 130001981279
• DOI: 10.1246/bcsj.61.2203
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/61/6/2203/55726874/bcsj.61.2203.pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可