An Improved Synthesis of <i>N</i>-Trifluoroacetyl-<scp>l</scp>-daunosamine

• Yoshikazu Kimura

  Sagami Chemical Research Center

• Teruyo Matsumoto

  Sagami Chemical Research Center

• Michiyo Suzuki

  Sagami Chemical Research Center

• Shiro Terashima

  Sagami Chemical Research Center

抄録

A process which can afford a large quantity of the title compound was explored by modifying the Horton’s original route. The developed process features highly stereoselective reduction of the oxime with sodium dihydrobis(2-methoxyethanolato)aluminate(1-) and efficient dehydrobromination with 1,8-diazabicyclo[5.4.0]undec-7-ene.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 59 (2), 663-664, 1986-02-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219102691840
• NII論文ID: 130001983175
• DOI: 10.1246/bcsj.59.663
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/59/2/663/55721933/bcsj.59.663.pdf
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