Colloidal Rhodium Dispersions Protected by Cyclodextrins

  • Makoto Komiyama
    Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo
  • Hidefumi Hirai
    Department of Industrial Chemistry, Faculty of Engineering, The University of Tokyo

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<jats:title>Abstract</jats:title> <jats:p>Refluxing of an aqueous solution of rhodium(III) chloride and α- or β-cyclodextrin, followed by further refluxing in the presence of ethanol, gives a colloidal dispersion of rhodium particles of 28 Å in diameter. The colloidal dispersion exhibits effective catalyses in hydrogena-tion of olefins at 30 °C under an atmospheric pressure.</jats:p>

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