The Rhodium Complex-catalyzed Synthesis of Quinolines from Aminoarenes and Aliphatic Aldehydes

• Yoshihisa Watanabe

  Department of Hydrocarbon Chemistry, Kyoto University

• Sang Chul Shim

  Department of Hydrocarbon Chemistry, Kyoto University

• Take-aki Mitsudo

  Department of Hydrocarbon Chemistry, Kyoto University

抄録

A variety of aminoarenes react with aliphatic aldehydes in the presence of a catalytic amount of a rhodium complex and an excess amount of the corresponding nitroarenes at 180 °C to give 2-alkyl- and 2,3-dialkyl-substituted quinolines in excellent yields. Among the rhodium complexes examined, [Rh(norbornadiene)Cl]2 exhibits the highest activity as a catalyst. Thus, 2-methyl-, 2-ethyl-3-methyl-, 2-propyl-3-ethyl-, and 2-butyl-3-propylquinoline derivatives are readily obtained from aminoarenes and ethanal, propanal, butanal, and pent-anal respectively.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 54 (11), 3460-3465, 1981-11-01

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360283694078344448
• NII論文ID: 130001987567
• DOI: 10.1246/bcsj.54.3460
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/54/11/3460/56105024/bcsj.54.3460.pdf
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