Anodic Oxidation of Methanol at a Pt Electrode in a Hydrophobic Room Temperature Ionic Liquid

• KUNIHIRO Yasushi

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

• KATAYAMA Yasushi

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

• MIURA Takashi

  Department of Applied Chemistry, Faculty of Science and Technology, Keio University

抄録

Anodic oxidation of methanol was investigated at a Pt electrode in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide (BMPTFSA) room temperature ionic liquid. It was found that methanol can be oxidized electrochemically in the ionic liquid without water. The oxidation products were identified as dimethoxymethane and proton by gas chromatography and electrochemical measurements. The further oxidation of dimethoxymethane was also suggested by cyclic voltammetry.

収録刊行物

• Electrochemistry

  Electrochemistry 77 (8), 647-648, 2009

  公益社団法人　電気化学会

キーワード

• Ionic Liquid
• Methanol Oxidation

詳細情報

• CRID: 1390001206495006464
• NII論文ID: 130002150623
• DOI: 10.5796/electrochemistry.77.647
• COI: 1:CAS:528:DC%2BD1MXhtVShsr%2FF
• ISSN: 21862451
• ISSN: 13443542
• Web Site: https://www.jstage.jst.go.jp/article/electrochemistry/77/8/77_8_647/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用可