Permeation Mechanism of Succinic Acid through Polymer Inclusion Membranes with Ionic Liquid Aliquat 336
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- Pratiwi Aulia Indah
- Department of Chemical Engineering and Materials Science, Faculty of Science and Engineering, Doshisha University
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- Sato Takehiro
- Department of Chemical Engineering and Materials Science, Faculty of Science and Engineering, Doshisha University
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- Matsumoto Michiaki
- Department of Chemical Engineering and Materials Science, Faculty of Science and Engineering, Doshisha University
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- Kondo Kazuo
- Department of Chemical Engineering and Materials Science, Faculty of Science and Engineering, Doshisha University
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抄録
A separation method for succinic acid has been intensively studied for developing cost-effective and environmentally benign processes. In this study, we applied polymer inclusion membranes (PIMs) containing an ionic liquid, Aliquat 336, to the separation of succinic acid. PIMs are formed by casting a solution containing a carrier, plasticizer, and base polymer (poly(vinyl chloride)) to form a thin, flexible, and stable film. We found that succinate successfully permeated the PIM containing Aliquat 336 and observed the uphill transport using a feed solution with pH 4 and Na2CO3 solution as the stripping phase. PIMs show complex permeation behavior involving un-dissociated, mono-anionic, and di-anionic forms of succinic acid as the species permeated. The mono-anionic form of succinic acid showed the largest permeability among the three forms, with the optimum pH range for succinic acid permeation being approximately 4–5.
収録刊行物
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- JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
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JOURNAL OF CHEMICAL ENGINEERING OF JAPAN 47 (4), 314-318, 2014
公益社団法人 化学工学会
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詳細情報 詳細情報について
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- CRID
- 1390282679545935744
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- NII論文ID
- 130003390892
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- NII書誌ID
- AA00709658
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- ISSN
- 18811299
- 00219592
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- NDL書誌ID
- 025601957
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可