Transition metal catalyzed borylation of functional π-systems

• SHINOKUBO Hiroshi

  Department of Applied Chemistry, Graduate School of Engineering, Nagoya University

抄録

Borylated functional π-systems are useful building blocks to enable efficient synthesis of novel molecular architectures with beautiful structures, intriguing properties and unique functions. Introduction of boronic ester substituents to a variety of extended π-systems can be achieved through either iridium-catalyzed direct C–H borylation or the two-step procedure via electrophilic halogenation followed by palladium-catalyzed borylation. This review article focuses on our recent progress on borylation of large π-conjugated systems such as porphyrins, perylene bisimides, hexabenzocoronenes and dipyrrins.

収録刊行物

• Ｐｒｏｃｅｅｄｉｎｇｓ　ｏｆ　ｔｈｅ　Ｊａｐａｎ　Ａｃａｄｅｍｙ．　Ｓｅｒ．　Ｂ：　Ｐｈｙｓｉｃａｌ　ａｎｄ　Ｂｉｏｌｏｇｉｃａｌ　Ｓｃｉｅｎｃｅｓ

  Ｐｒｏｃｅｅｄｉｎｇｓ　ｏｆ　ｔｈｅ　Ｊａｐａｎ　Ａｃａｄｅｍｙ．　Ｓｅｒ．　Ｂ：　Ｐｈｙｓｉｃａｌ　ａｎｄ　Ｂｉｏｌｏｇｉｃａｌ　Ｓｃｉｅｎｃｅｓ 90 (1), 1-11, 2014

  日本学士院

キーワード

• transition-metal catalyst
• C–H activation
• boron
• porphyrin
• polyaromatic hydrocarbons
• BODIPY

詳細情報

• CRID: 1390282679124061056
• NII論文ID: 130003392349
• NII論文ID: 40019947142
• NII書誌ID: AA00785485
• DOI: 10.2183/pjab.90.1
• COI: 1:STN:280:DC%2BC2cvhvVCgug%3D%3D
• ISSN: 13492896
• ISSN: 03862208
• NDL書誌ID: 025155258
• PubMed: 24492644
• Web Site: https://ndlsearch.ndl.go.jp/books/R000000004-I025155258
• Web Site: https://www.jstage.jst.go.jp/article/pjab/90/1/90_1/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • NDL
  • Crossref
  • PubMed
  • CiNii Articles
  • KAKEN
• 抄録ライセンスフラグ: 使用不可