Fine Structure of Multi-particle Layered Organization for Organo-modified Zirconium Dioxides Fabricated by the Langmuir-Blodgett Technique
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- Iwashita Hayato
- Department of Functional Materials Science, Faculty of Engineering, Saitama University
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- Hakozaki Sho
- Graduate School of Science and Engineering, Yamagata University
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- Kawaguchi Seigou
- Graduate School of Science and Engineering, Yamagata University
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- Fujimori Atsuhiro
- Graduate School of Science and Engineering, Saitama University
抄録
Formation and structure of organo-modified zirconium dioxides of multi-particle layered organization were investigated by out-of plane and in-plane X-ray diffraction (XRD) and atomic force microscopy (AFM). The surface modification of zirconia particle was performed by several long-chain carboxylic acids with different lengths. Langmuir monolayers of these particles were extremely condensed on the water surface. Multi-particle layered organization was constructed by the Langmuir-Blodgett (LB) technique. From the results of out-of plane XRD measurement of the multilayers of oleic acid-modified ZrO2 particles, a sharp peak was clearly observed at 52 Å. AFM image at mesoscopic scales of this single particle layer show particle assembly at 50 nm diameters. However, fine particles at about 5 nm diameters are confirmed in the case of high-resolution AFM observation to the mono-particle films transferred at low surface pressure region. Therefore, it is found that regular periodic structure along the c-axis and a hierarchical aggregated particle form were fabricated by Langmuir and LB technique.
収録刊行物
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- Transactions of the Materials Research Society of Japan
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Transactions of the Materials Research Society of Japan 37 (2), 299-302, 2012
一般社団法人 日本MRS
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詳細情報 詳細情報について
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- CRID
- 1390282680489154688
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- NII論文ID
- 130003399106
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- COI
- 1:CAS:528:DC%2BC38Xht1aksLrO
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- ISSN
- 21881650
- 13823469
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可