A Novel Type of Organic Semiconductors. Molecular Fastener

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<jats:title>Abstract</jats:title> <jats:p>The electrical conductivity of alkylthio-substituted tetrathiafulvalene (TTCn-TTF) single crystal has been measured in a vacuum of 10−4 Pa with the two probe method. The room temperature dark conductivity of TTC10-TTF reaches 10−5 S cm−1, a value that is extraordinarily high compared with those of other organic semiconductors constructed with a single component. The cause of this high conductivity is that the central tetrathiafulvalene skeleton has been fastened strongly with the four long alkyl chains.</jats:p>

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  • Chemistry Letters

    Chemistry Letters 15 (8), 1263-1266, 1986-08

    Oxford University Press (OUP)

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