Reaction of Stabilized Bismuthonium Ylides with Aldehydes. A Novel Reaction Mode of the Heaviest Group V Element Ylide

• Takuji Ogawa

  Department of Chemistry, Faculty of Science, Ehime University

• Toshihiro Murafuji

  Department of Chemistry, Faculty of Science, Ehime University

• Hitomi Suzuki

  Department of Chemistry, Faculty of Science, Ehime University

抄録

Stabilized bismuthonium ylides, triphenylbismuthonio-4,4-dimethyl-2,6-dioxocyclohexane-1-ide and triphenylbismuthonio-4,4-dimethyl-2,6-dioxo-3,5-dioxan-1-ide, react with aldehydes to afford three types of products; tetraacylcyclopropanes, dihydrofurans, and α,β-unsaturated carbonyl compounds, the relative importance of these depending greatly on the ylides, aldehydes, and reaction conditions employed.

収録刊行物

• Chemistry Letters

  Chemistry Letters 17 (5), 849-852, 1988-05

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360002219108082816
• NII論文ID: 130003414854
• DOI: 10.1246/cl.1988.849
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/17/5/849/55651913/cl.1988.849.pdf
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