Activity Measurements of the PbO&ndash;SiO<SUB>2</SUB> Melts by the TIE Method

  • Okajima Kazuhisa
    Department of Metallurgy, Faculty of Engineering, Nagoya University
  • Sakao Hiroshi
    Department of Metallurgy, Faculty of Engineering, Nagoya University

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  • Activity Measurements of the PbO–SiO<SUB>2</SUB> Melts by the TIE Method

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The present study was carried out so as to ascertain whether or not the TIE method can be applied with good accuracy at higher temperatures. The activities of component PbO in the PbO–SiO2 melt were measured at 950 and 1050°C.<BR>In the moment the standard melt (NPbO=0.928) makes contact with both electrodes, the concentration cell is constituted as follows:<BR>Pb|PbO–SiO2 (standard)|PbO–SiO2 (measuring)|Pb.<BR>It was found that the experimental results were satisfactory compared with the datain the literature and the values calculated thermodynamically for the compounds PbSiO3 and Pb2SiO4.

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