Solubility of Oxides in Liquid Alloys Containing Titanium and Zirconium

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The oxygen solubility curves for Fe–Ti–O, Co–Ti–O, Ni–Ti–O, Fe–Zr–O . Co–Zr–O and Ni–Zr–O alloys saturated with oxides of titanium and zirconium were calculated. The experimental data of Fe–Ti–O and Fe–Zr–O systems from the literature correlate reasonably well with the calculated curves from the model by Wagner and the empirical correlation of Chiang and Chang over the temperature range of 1823 K to 2073 K . The Gibbs energies of oxygen in liquid titanium, ΔGO(Ti)° and zirconium, ΔGO(Zr)° were also estimated.

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