Influence of Heat Treatment Conditions on Mechanical Properties of Hydrogenated Type 304 Stainless Steel at Low Temperatures

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The influence of hydrogen on the mechanical properties of Type 304 stainless steel at low temperatures was studied using specimens solution-annealed at 1373 K (1100°C) for 1.8 ks (30 min), in part sensitized at 1073 K (800°C) for 1.8 ks (30 min) and/or hydrogenated by cathodic charging at 323 K (50°C) in 0.5N sulfuric acid solution.<BR>Principal results obtained are as follows:<BR>(1) When tested at 77 K (−196°C), the sensitized and hydrogenated specimens exhibited singular low-temperature hydrogen embrittlement (LTHE).<BR>(2) Non-sensitized specimens hydrogenated and tested under the same conditions showed no such singular embrittlement.<BR>(3) Fracture surfaces of specimens that had exhibited singular LTHE behavior revealed an almost wholly intergranular fracture pattern.<BR>(4) Hydrogenated specimens exhibited partial recovery of ductility upon dehydrogenation treatment at 1073 K (800°C) or lower temperature.<BR>(5) The activation energy governing the recovery process was 51 kJ/mol.

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