Interdiffusion in α Solid Solutions of Cu–Al–Zn System

  • Takahashi Tomoshi
    Department of Metallurgical Engineering, Niihama National College of Technology
  • Kato Michitomo
    Department of Metallurgical Engineering, Niihama National College of Technology
  • Minamino Yoritoshi
    Department of Materials Science and Engineering, Faculty of Engineering, Osaka University
  • Yamane Toshimi
    Department of Materials Science and Engineering, Faculty of Engineering, Osaka University

書誌事項

タイトル別名
  • Interdiffusion in α Solid Solutions of Cu–Al–Zn System

抄録

The interdiffusion coefficients in the α-phase of Cu–Al–Zn alloys \ ildeDZnZnCu, \ ildeDZnAlCu, \ ildeDAlAlCu and \ ildeDAlZnCu have been determined by an extended Boltzmann-Matano method in a temperature range from 1043 to 1203 K. All of the four interdiffusion coefficients are positive, and they are very sensitive to the solute concentration. The activation energies for the interdiffusion of the ternary alloys are similar to those for the tracer diffusion of Cu–Al and Cu–Zn binary alloys. Large positive interaction parameters εZn(Al) and εAl(Zn) indicate that Al and Zn atoms in the Cu–Al–Zn alloys have repulsive force between each other.

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