REGIOSELECTIVE POLYPRENYL REARRANGEMENT OF POLYPRENYL 2,3,4,5-TETRASUBSTITUTED PHENYL ETHERS PROMOTED BY BORON TRIFLUORIDE

• Toyokichi Yoshizawa

  Research Institute, Wakamoto Pharmaceutical Co., Ltd

• Hatsunori Toyofuku

  Research Institute, Wakamoto Pharmaceutical Co., Ltd

• Koichi Tachibana

  Research Institute, Wakamoto Pharmaceutical Co., Ltd

• Toshio Kuroda

  Research Institute, Wakamoto Pharmaceutical Co., Ltd

抄録

4-Acetoxy-6-polyprenyl-2,3,5-trimethylphenols or 2,3-dimethoxy-5-methyl-6-polyprenylhydroquinones were obtained selectively by the BF3·OEt2 catalyzed polyprenyl rearrangement of polyprenyl 4-acetoxy-2,3,5-trimethylphenyl ethers or polyprenyl 2,3-dimethoxy-4-hydroxy-5-methylphenyl ethers.

収録刊行物

• Chemistry Letters

  Chemistry Letters 11 (8), 1131-1134, 1982-08

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360846644037263360
• NII論文ID: 130003518195
• DOI: 10.1246/cl.1982.1131
• ISSN: 13480715
• ISSN: 03667022
• Web Site: https://academic.oup.com/chemlett/article-pdf/11/8/1131/56222771/cl.1982.1131.pdf
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