Brillouin Scattering Study of the Ferroelastic Phase Transition of BiVO4

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  • Brillouin Scattering Study of the Ferroelastic Phase Transition of BiVO<SUB>4</SUB>
  • Brillouin Scattering Study of the Ferro

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The elastic instability in the ferroelastic phase transition of BiVO4 was investigated by the observation of the Brillouin scattering spectra as a function of temperature around the transition temperature. From the temperature dependence of the observed spectra in two different scattering geometries it turns out clear that the softening of elastic stifiness constant c11c12, not of c66, causes the ferroelastic transition. The elastic softening is discussed in connection with the domain structure.

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