Hydrogen Exchange Reaction of Aminobenzoic Acid. I. Comparison between Wilzbach Tritiation and Acid Catalyzed Hydrogen Exchange Reaction
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Wilzbach tritiation in ortho-, meta- and para-aminobenzoic acids was compared with acid catalysed hydrogen exchange reaction and bromination. The acid catalysed hydrogen exchange reaction of the acids in 4 N DCl occurred at ortho and para to amino group of the acids and it was confirmed that the reaction was a typical electrophilic substitution. Tritium incorporation in the acids by Wilzbach labelling was high at ortho and para to amino group of the acids although the order of reactivity on Wilzbach labelling did not completely agreed with that in acid hydrogen exchange reaction. This seems to suggest that HeT+ ion would participate in the labelling predominantly.
収録刊行物
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- CHEMICAL & PHARMACEUTICAL BULLETIN
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CHEMICAL & PHARMACEUTICAL BULLETIN 17 (3), 495-498, 1969
公益社団法人 日本薬学会
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詳細情報 詳細情報について
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- CRID
- 1390001204173262464
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- NII論文ID
- 110003620915
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- NII書誌ID
- AA00602100
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- ISSN
- 13475223
- 00092363
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可