Thiosteroids. XXV. Syntheses of the Epimers of Cholest-4-and-5-en-2, 3-episulfide and Related Compounds

• 米野 太一郎

• 井谷 光

抄録

Cholest-4-en-2β, 3β-episulfide and the epimers of cholest-5-en-2, 3-episulfide were synthesized upon treatment of the corresponding thiocyanatohydrin acetate with alkali. However, synthesis of cholest-4-en-2α, 3α-episulfide in a similar way failed. This could be achieved successfully but in low yield by treatment of 3β-acetoxycholest-4-en-2α-ethyl xanthate with alkali. CD and ORD curves of these episulfides were studied.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 18 (3), 608-616, 1970

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390001204172018176
• NII論文ID: 110003632338
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.18.608
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/18/3/18_3_608/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1971046326
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可