Studies on Metabolism of 3-Deoxysteroids. IV. Synthesis of 2, 17-Oxygenated 5-Dehydro- and 5β-Androstanes

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For the studies on metabolic fate of 3-deoxydehydroepiandrosterone in man, 5-dehydro- and 5β-androstanes having oxygen functions at both C-2 and C-17, the possible metabolites, have been synthesized as shown in Chart 1.

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