Effect of Water on Rate of Charge-Transfer Reaction of Aniline with Chloranil

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Charge-transfer (CT) is known to take part in various complexations and reactions. Because the most phenomena of pharmaceutical interest occur in aqueous media, the effect of water on CT has become an important subject in the pharmaceutical field. The previous study has demonstrated that water promotes the formation of outer complexes. In the present study, attention has been drawn to the rate of CT reaction. As the example in this work, aniline-chloranil system has been taken on which detailed studies carried out with respect to the outer complex formation and the CT reaction.

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