Selenabenzenes. II. Reaction Mechanism of 9-Phenylselenoxanthylium Salt with Organometallic Reagents. On 10-Selenaanthracene and Selenoxanthene Derivatives

• 堀 幹夫

• 片岡 貞

• 清水 洋

• 許 振福

• 朝日 豊

• 水田 栄治

抄録

The mechanism of the reactions between 9-phenylselenoxanthylium perchlorate (IIb) with phenyllithium or Grignard reagents was clarified by the studies of the eloctron spin resonancl spectroscopy and the chemical reactivities of 9-phenylselenoxanthyl radical (V), which was a reaction intermediate. These experimental results show that the radical mechanism considerably contributes to the reactions between IIIb and organometallic reagents.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 22 (1), 32-41, 1974

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390001204176870784
• NII論文ID: 110003632968
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.22.32
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/22/1/22_1_32/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1974082020
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可