Chemical studies on breynin A, breynogenin and breynolide.

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The structure of breynogenin (C22H26O9S), an aglycone of breynin A, was established as III on the basis of chemical and spectral investigations. The structure of isobreynogenin (C22H26O9S), a secondary degradation product from breynin A, was determined as IV. Partial structure for breynin A has been presumed.

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