Structure of tryptoquivaline C (FTC) and D (FTD). Novel fungal metabolites from Aspergillus fumigatus.

• 山崎 幹夫

• 藤本 治宏

• 奥山 恵美

抄録

Structures of tryptoquivaline C and D, isolated from Aspergillus fumigatus were determined as I and II. The stereostructure of I was determined by direct comparison of I with tryptoquivaline which structure was determined by X-ray analysis already. Stereostructure of II was determined by comparison of its spectral data with that of I and from the result that compound A (VIa or b) was obtained on oxidation of both I and II. Since L-(+)-alanine was obtained by hydrolysis of a reduction product from II, S-configuration was proposed on the stereochemistry of C-15 in II.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 25 (10), 2554-2560, 1977

  公益社団法人 日本薬学会

キーワード

• Aspergillus fumigatus

詳細情報

• CRID: 1390282679146164736
• NII論文ID: 110003622229
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.25.2554
• COI: 1:CAS:528:DyaE1cXjsVeisA%3D%3D
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/25/10/25_10_2554/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1978106895
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可