Facile Desulfurization of Thiocarbonyl Groups to Carbonyls by Superoxide. A Model of Metabolic Reactions

• 香取 悦

• 長野 哲雄

• 国枝 武久

• 広部 雅昭

抄録

Several types of thioamides and thioureas including thiouracils were readily desulfurized to the carbonyl compounds by superoxide, generated by KO₂ and 18-crown-6 or electrolysis of oxygen in aprotic solvent at room temperature. Such desulfurization may provide a model of metabolic reactions catalyzed by oxygenases.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 29 (10), 3075-3077, 1981

  公益社団法人 日本薬学会

キーワード

• thiocarbonyl

詳細情報

• CRID: 1390001204171342720
• NII論文ID: 130003768882
• DOI: 10.1248/cpb.29.3075
• COI: 1:CAS:528:DyaL38XnvFeltg%3D%3D
• ISSN: 13475223
• ISSN: 00092363
• PubMed: 6274522
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/29/10/29_10_3075/_pdf
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • PubMed
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可