Studies on photochemical reactions of air pollutants. VIII. Photochemical epoxidation of olefins with NO2 in a solid-gas phase system.
抄録
Upon irradiation with a xenon lamp through a Pyrex filter (cut-off below 290 nm), olefinic compounds such as trans-stilbene, cyclohexene, 4, 5-dibromocyclohexene and aldrin reacted with nitrogen dioxide, an air pollutant which induces photochemical smog, in air and gave the corresponding epoxides in good yields, while phenanthrene gave 9, 10-phenanthrenequinone and 9-hydroxy-10-nitrophenanthrene. Furthermore, the photochemical and dark reactions of phenanthrene 9, 10-oxide with nitrogen dioxide in air both resulted in the same products as above. Therefore, phenanthrene 9, 10-oxide seems to be an intermediate in the photochemical reaction of phenanthrene with nitrogen dioxide in air.
収録刊行物
-
- CHEMICAL & PHARMACEUTICAL BULLETIN
-
CHEMICAL & PHARMACEUTICAL BULLETIN 30 (12), 4500-4506, 1982
公益社団法人 日本薬学会
- Tweet
詳細情報 詳細情報について
-
- CRID
- 1390001204166498816
-
- NII論文ID
- 130003769081
-
- COI
- 1:CAS:528:DyaL3sXitVemur4%3D
-
- ISSN
- 13475223
- 00092363
- http://id.crossref.org/issn/00092363
-
- 本文言語コード
- en
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可