Regio- and stereoselective functionalizations of the Wieland-Miescher ketone derivatives at the C-8 position.

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Abstract

New efficient methods for stereoselective hydroxymethylation, hydroxylation, and thiophenylation at the C-8 position of the Wieland-Miescher ketone derivatives (2__--4__-) have been developed by diverse modifications from the Kirk-Petrow reaction, which involve autoxidation for the hydroxylation.

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