Studies on the Steroidal Components of Domestic Plants. XXXV. Structure of Meteogenin. (1).

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The structure of meteogenin, isolated from the rhizome of Metanarthecium luteoviride MAXIM., was shown to be 1-methyl-19-nor-25D-spirosta-1, 3, 5 (10)-trien-11α-ol (IIa). The relationship between luvigenin (I) and meteogenin (IIa) was established, and at the same time it was proved that the direction of the dienol-benzene rearrangement varied according to the presence of the double bond at C6 or of the C11-ketone.

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