In Situ Fluorescence Microscopic Measurements of Complexation Reactions at Liquid/Liquid Interface

• TSUKAHARA Satoshi

  Department of Chemistry, Graduate School of Science, Hiroshima University

抄録

In situ microscopic measurement is a novel approach to clarify the intrinsic mechanism of complexation reactions occurring at liquid/liquid interfaces. The present review was mainly focused on recent three topics of methodology of in situ fluorescence microscopic observation and measurement of interfacial complexation reactions: (1) two kinds of self-assemblies of Pd²⁺ and 5, 10, 15, 20-tetra (4-pyridy1)-21H, 23H-porphine complexes formed at the toluene/water interface, (2) microextraction of Eu³⁺ with 2- thenoyltrifluoroacetone at the dodecane/water interface, (3) rapid complexation of Zn²⁺ with 5- octyloxymethy1-8-quinolinol in the 1-butanol/water interfacial region. The inhomogeneities of adsorption and reaction of complexes or the fast complexation rate at the liquid/liquid interface was measurable only by the microscopic methods.

収録刊行物

• Ｉｎｔｅｒｎａｔｉｏｎａｌ　Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｍａｔｅｒｉａｌｓ　Ｅｎｇｉｎｅｅｒｉｎｇ　ｆｏｒ　Ｒｅｓｏｕｒｃｅｓ

  Ｉｎｔｅｒｎａｔｉｏｎａｌ　Ｊｏｕｒｎａｌ　ｏｆ　ｔｈｅ　Ｓｏｃｉｅｔｙ　ｏｆ　Ｍａｔｅｒｉａｌｓ　Ｅｎｇｉｎｅｅｒｉｎｇ　ｆｏｒ　Ｒｅｓｏｕｒｃｅｓ 13 (1), 1-8, 2005

  日本素材物性学会

キーワード

• Liquid/liquid interface
• In situ fluorescence microscopy
• Solvent extraction
• Complexation reaction
• Self-assembly adsorption

詳細情報

• CRID: 1390001205199841280
• NII論文ID: 130003920843
• NII書誌ID: AA1095475X
• DOI: 10.5188/ijsmer.13.1
• ISSN: 18846629
• ISSN: 13479725
• HANDLE: 10295/682
• Web Site: https://air.repo.nii.ac.jp/records/893
• 本文言語コード: en
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