A Nuclear Magnetic Resonance Study of the Curzerenone

• 植松 正吾

• 赤堀 幸男

• 福島 清吾

• 斎木 保久

• 上野 明

• 黒柳 正典

抄録

The high-resolution proton magnetic resonance spectra of curzerenone observed in 20 mole percent solution in carbon tetrachloride and deuterochloroform were analyzed with the aid of the computation and the double resonance experiments. The relative sign of the coupling constants was determined by the spin-tickling method, and the accurate values of parameters were obtained. It was confirmed the presence of the long-range spin coupling ⁵J_H<SUB>H</SUB> via the ether linkage in the fused furan ring, and the values of nuclear magnetic resonance parameters were shown to be reasonable for the predicted structure.

収録刊行物

• ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ

  ＣＨＥＭＩＣＡＬ　＆　ＰＨＡＲＭＡＣＥＵＴＩＣＡＬ　ＢＵＬＬＥＴＩＮ 18 (6), 1118-1123, 1970

  公益社団法人 日本薬学会

キーワード

• Drug Discovery
• General Chemistry
• General Medicine

詳細情報

• CRID: 1390282679149218048
• NII論文ID: 110003632436
• NII書誌ID: AA00602100
• DOI: 10.1248/cpb.18.1118
• ISSN: 13475223
• ISSN: 00092363
• Web Site: http://www.jstage.jst.go.jp/article/cpb1958/18/6/18_6_1118/_pdf
• Web Site: https://search.jamas.or.jp/link/ui/1971045970
• 本文言語コード: en
• データソース種別:
  • JaLC
  • Crossref
  • CiNii Articles
• 抄録ライセンスフラグ: 使用不可