Hg²⁺-Trapping Beads : Hg²⁺-Specific Recognition through Thymine-Hg(Ⅱ)-Thymine Base Pairing

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  • Hg<sup>2+</sup>-Trapping Beads: Hg<sup>2+</sup>-Specific Recognition through Thymine–Hg(II)–Thymine Base Pairing

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Mercury pollution poses a severe threat to human health. To remove Hg2+ from contaminated water, we synthesized Hg2+-trapping beads that include oligo-thymidine functionalities that can form thymine–Hg(II)–thymine base pairs on the solid support. The beads can selectively trap Hg2+ even in the presence of other metal cations. More interestingly, Hg2+-trapping efficiency was higher in the presence of the co-existing cations. Thus, the developed Hg2+-trapping beads can capture Hg2+ without affecting the mineral balance of water so much. The Hg2+-trapping beads presented here show promise for removing Hg2+ from environmental water.

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