Synthesis of .BETA.-Hydroxy Nitriles via Indium-Induced Coupling of Bromoacetonitrile with Carbonyl Compounds.

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著者

    • Araki Shuki
    • Department of Applied Chemistry, Nagoya Institute of Technology
    • Butsugan Yasuo
    • Department of Applied Chemistry, Nagoya Institute of Technology

抄録

The organoindium reagent, derived from indium metal and bromoacetonitrile, reacted with carbonyl compounds in the presence of chlorotrimethylsilane to give, after hydrolysis, <i>β</i>-hydroxy nitriles. The coupling proceeded with high chemoselectivity, though the diastereoselectivity was low.

収録刊行物

  • Bulletin of the Chemical Society of Japan

    Bulletin of the Chemical Society of Japan 67(4), 1126-1129, 1994

    公益社団法人 日本化学会

各種コード

  • NII論文ID(NAID)
    130004148671
  • 本文言語コード
    ENG
  • ISSN
    0009-2673
  • データ提供元
    J-STAGE 
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