Electronic Structure of Yttrium and Carbon Atoms Encapsulated Metallofullerenes, Y2C2@C82: Ultraviolet Photoelectron Spectroscopy and Theoretical Calculation

• Shojun Hino

  Graduate School of Science and Engineering, Ehime University

• Takafumi Miyazaki

  Graduate School of Science and Engineering, Ehime University

• Yusuke Aoki

  Graduate School of Science and Engineering, Ehime University

• Norihiko Wanita

  Graduate School of Science and Technology, Chiba University

• Masayuki Kato

  Graduate School of Science and Technology, Chiba University

• Ryohei Sumii

  UVSOR, Institute for Molecular Science

• Takao Akachi

  Graduate School of Science, Nagoya University

• Takeshi Inoue

  Graduate School of Science, Nagoya University

• Yasuhiro Ito

  Graduate School of Science, Nagoya University

• Toshiki Sugai

  Graduate School of Science, Nagoya University

• Hisanori Shinohara

  Graduate School of Science, Nagoya University

抄録

Ultraviolet photoelectron spectra (UPS) of two yttrium atoms and two carbon atoms encapsulated metallofullerenes, Y2C2@C82 were measured using a synchrotron radiation light source. Their upper valence band UPS differ significantly from each other, while the lower valence band ones are almost the same. The UPS of Y2C2@C82 (II) could be well reproduced by simulated spectra obtained with a Gaussian 03 program module assuming a distorted Y2C2 tetragonal form in C2v C82 cage structure.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 82 (8), 963-967, 2009-08

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169058753152
• NII論文ID: 130004152649
• DOI: 10.1246/bcsj.82.963
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/82/8/963/56271122/bcsj.82.963.pdf
• データソース種別:
  • Crossref
  • CiNii Articles