Synthesis and Structures of a Series of Bulky “Rind-Br” Based on a Rigid Fused-Ring <i>s</i>-Hydrindacene Skeleton

• Tsukasa Matsuo

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Katsunori Suzuki

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Tomohide Fukawa

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Baolin Li

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Mikinao Ito

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Yoshiaki Shoji

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Takashi Otani

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Liangchun Li

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Megumi Kobayashi

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Makoto Hachiya

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Yoshiyuki Tahara

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

• Daisuke Hashizume

  Advanced Technology Support Division, RIKEN Advanced Science Institute

• Takeo Fukunaga

  Advanced Technology Support Division, RIKEN Advanced Science Institute

• Aiko Fukazawa

  International Research Center for Elements Science (IRCELS), Institute for Chemical Research, Kyoto University

• Yongming Li

  International Research Center for Elements Science (IRCELS), Institute for Chemical Research, Kyoto University

• Hayato Tsuji

  International Research Center for Elements Science (IRCELS), Institute for Chemical Research, Kyoto University

• Kohei Tamao

  Functional Elemento-Organic Chemistry Unit, RIKEN Advanced Science Institute

抄録

A series of octa-R-substituted bromo-s-hydrindacenes, “Rind-Br,” have been synthesized by a sequence of the Lewis acid catalyzed intramolecular Friedel–Crafts reaction, bromination and vice versa. Their structural features and physical properties depend on the eight R-substituents at the four benzylic positions on the s-hydrindacenyl skeleton. The molecular structures of the Rind-Br have been confirmed by X-ray crystallography, indicating the unique structural diversities of the bulky Rind groups.

収録刊行物

• Bulletin of the Chemical Society of Japan

  Bulletin of the Chemical Society of Japan 84 (11), 1178-1191, 2011-10-29

  Oxford University Press (OUP)

キーワード

• General Chemistry

詳細情報

• CRID: 1360565169050241024
• NII論文ID: 130004152829
• DOI: 10.1246/bcsj.20110090
• ISSN: 13480634
• ISSN: 00092673
• Web Site: https://academic.oup.com/bcsj/article-pdf/84/11/1178/56273055/bcsj.20110090.pdf
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