Synthesis of New Perovskite-Type Oxyfluoride, PbMnO2F

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<jats:title>Abstract</jats:title> <jats:p>New perovskite-type oxyfluoride, PbMnO2F was synthesized under 4–7 GPa at 1000 °C. As a result of X-ray and electron diffractions, the compound was determined to have tetragonal perovskite structure with a × a × 4c super structure where a and c are the lattice parameters of the perovskite subcell. The tetragonality, c/a, attained maximum, c/a = 1.100, for PbMnO2F synthesized under 4 GPa.</jats:p>

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